Publications

43. Coupling of α-bromoamides and unactivated alkenes to form γ-lactams through EDA and photocatalysis

Treacy, S. M.; Vaz, D. R.; Noman, S.; Tard, C.; Rovis, T.

Chem. Sci. 2023, 14 (6), 1569-1574.

42. Offshore CO2 capture and utilization using floating wind/PV systems: site assessment and efficiency analysis in the Mediterranean

Keller, D.; Somanna, V.; Drobinski, P.; Tard, C.

Energies 2022, 15 (23), 8873.

41. Green synthesis of water splitting electrocatalysts: IrO2 nanocages via Pearson's chemistry

Elmaalouf, M.; Da Silva, A.; Duran, S.; Tard, C.; Comesana-Hermo, M.; Gam Derouich, S.; Briois, V.; Alloyeau, D.; Giraud, M.; Piquemal, J.-Y.; Peron, J.

Chem. Sci. 2022, 13 (40), 11807-11816.

40. Electrochemical active surface area determination of iridium-based mixed oxides by mercury underpotential deposition

Duran, S.; Elmaalouf, M.; Odziomek, M.; Piquemal, J.-Y.; Faustini, M.; Giraud, M.; Peron, J.; Tard, C.

ChemElectroChem 2021, 8 (18), 3519-3524

39. The origin of the high electrochemical activity of pseudo-amorphous iridium oxides

Elmaalouf, M.; Odziomek, M.; Duran, S.; Gayrard, M.; Bahri, M.; Tard, C.; Zitolo, A.; Lassalle-Kaiser, B.; Piquemal, J.-Y.; Ersen, O.; Boissière, C.; Sanchez, C.; Giraud, M.; Faustini, M.; Peron, J.

Nat. Commun. 2021, 12 (1), 3935

38. A pioneering career in electrochemistry: Jean-Michel Savéant

Costentin, C.; Limoges, B.; Robert, M.; Tard, C.

ACS Catal. 2021, 11 (6), 3224-3238

37. Aerosol synthesis of thermally stable porous noble metals and alloys by using bi-functional templates

Odziomek, M.; Bahri, M.; Boissière, C.; Sanchez, C.; Lassalle-Kaiser, B.; Zitolo, A.; Ersen, O.; Nowak, S.; Tard, C.; Giraud, M.; Faustini, F.; Peron, J.

Mater. Horiz. 2020, 7 (2), 541-550

36. Rational de novo design of a Cu-metalloenzyme for superoxide dismutation

Mathieu, E.; Tolbert, A. E.; Koebke, K. J.; Tard, C.; Iranzo, O.; Penner-Hahn, J. E.; Policar, C.; Pecoraro, V.

Chem. Eur. J. 2020, 26 (1), 249-258

35. Traversing the red-green-blue color spectrum in rationally designed cupredoxins

Koebke, K. J.; Sosa Alfaro, V.; Pinter, T. B. J.; Deb, A.; Lehnert, N.; Tard, C.; Penner-Hahn, J. E.; Pecoraro, V. L.

J. Am. Chem. Soc. 2020, 142 (36), 15282-15294

34. Electronic communication between dithiolato-bridged diiron carbonyl and S-bridged redox-active centres

Tard, C.; Borg, J. S.; Fairhurst, A. S.; Pickett, J. C.; Best, P. S.

Inorganics 2019, 7 (3), 37

33. Hierarchically structured ultraporous iridium-based materials: a novel catalyst architecture for proton exchange membrane water electrolyzers

Faustini, M.; Giraud, M.; Jones, D.; Rozière, J.; Dupont, M.; Porter, T. R.; Nowak, S.; Bahri, M.; Ersen, O.; Sanchez, C.; Boissière, C.; Tard, C.; Peron, J.

Adv. Energy Mater. 2019, 9 (4), 1802136

32. pH-dependence on HER electrocatalytic activity of iron sulfide pyrite nanoparticles

Villalba, M.; Peron, J.; Giraud, M.; Tard, C.

Electrochem. Commun. 2018, 91, 10-14

31. Development of a rubredoxin-type center embedded in a de novo designed three-helix bundle

Tebo, A.; Pinter, T. B. J.; García-Serres, R.; Speelman, A. L.; Tard, C.; Sénèque, O.; Blondin, G.; Latour, J.-M.; Penner-Hahn, J. E.; Lehnert, N.; Pecoraro, V. L.

Biochemistry 2018, 57 (16), 2308-2316

30. Clarifying the copper coordination environment in a de novo designed red copper protein

Koebke, K. J.; Ruckthong, L.; Meagher, J. L.; Mathieu, E.; Harland, J.; Deb, A.; Lehnert, N.; Policar, C.; Tard, C.; Penner-Hahn, J. E.; Stuckey, J. A.; Pecoraro, V. L.

Inorg. Chem. 2018, 57 (19), 12291-12302

29. Ligand “noninnocence” in coordination complexes vs. kinetic, mechanistic, and selectivity issues in electrochemical catalysis

Costentin, C.; Savéant, J.-M.; Tard, C.

Proc. Natl. Acad. Sci. U. S. A. 2018, 115 (37), 9104-9109

28. Catalysis of CO2 electrochemical reduction by protonated pyridine and similar molecules. Useful lessons from a methodological misadventure

Costentin, C.; Savéant, J.-M.; Tard, C.

ACS Energy Lett. 2018, 3 (3), 695-703

27. Hollow iridium-based catalysts for the oxygen evolution reaction in proton exchange membrane water electrolyzers

Peron, J.; Faustini, M.; Giraud, M.; Rozière, J.; Jones, D. J.; Boissière, C.; Tard, C.

ECS Trans. 2017, 80 (8), 1077-1084

26. Nanodiffusion in electrocatalytic films

Costentin, C.; Di Giovanni, C.; Giraud, M.; Savéant, J.-M.; Tard, C.

Nat. Mat. 2017, 16 (10), 1016-1021

25. Attempts to catalyze the electrochemical CO2-to-methanol conversion by biomimetic 2e-+2H+ transferring molecules

Savéant, J.-M.; Tard, C.

J. Am. Chem. Soc. 2016, 138 (3), 1017-1021

24. Low-cost nanostructured iron sulfide electrocatalysts for PEM water electrolysis

Di Giovanni, C.; Reyes-Carmona, Á.; Coursier, A.; Nowak, S.; Grenèche, J.-M.; Lecoq, H.; Mouton, L.; Rozière, J.; Jones, D. J.; Peron, J.; Giraud, M.; Tard, C.

ACS Catal. 2016, 6 (4), 2626-2631

23. Conductive mesoporous catalytic films. Current distortion and performance degradation by dual-phase ohmic drop effects. Analysis and remedies

Andrieux, C. P.; Costentin, C.; Di Giovanni, C.; Savéant, J.-M.; Tard, C.

J. Phys. Chem. C 2016, 120 (38), 21263-21271

22. De novo design and characterization of copper metallopeptides inspired by native cupredoxins

Plegaria, J. S.; Duca, M.; Tard, C.; Friedlander, T. J.; Deb, A.; Penner-Hahn, J. E.; Pecoraro, V. L.

Inorg. Chem. 2015, 54 (19), 9470-9482

21. Proton-coupled electron transfer in azobenzene-hydrazobenzene couples with pending acid-base functions. Hydrogen-bonding and structural effects

Savéant, J.-M.; Tard, C.

J. Am. Chem. Soc. 2014, 136 (25), 8907-8910

20. Bioinspired iron sulfide nanoparticles for cheap and long-lived electrocatalytic molecular hydrogen evolution in neutral water

Di Giovanni, C.; Wang, W.-A.; Nowak, S.; Grenèche, J.-M.; Lecoq, H.; Mouton, L.; Giraud, M.; Tard, C.

ACS Catal. 2014, 4 (2), 681-687

19. Breaking bonds with electrons and protons. Models and examples

Costentin, C.; Robert, M.; Savéant, J.-M.; Tard, C.

Acc. Chem. Res. 2014, 47 (1), 271-280

18. Hydrogen-bond relays in concerted proton–electron transfers

Bonin, J.; Costentin, C.; Robert, M.; Savéant, J.-M.; Tard, C.

Acc. Chem. Res. 2012, 45 (3), 372-381

17. Thermochromic luminescence of copper iodide clusters: the case of phosphine ligands

Perruchas, S.; Tard, C.; Le Goff, X. F.; Fargues, A.; Garcia, A.; Kahlal, S.; Saillard, J.-Y.; Gacoin, T.; Boilot, J.-P.

Inorg. Chem. 2011, 50 (21), 10682–10692

16. H-bond relays in proton-coupled electron transfers. Oxidation of a phenol concerted with proton transport to a distal base through an OH relay

Costentin, C.; Robert, M.; Savéant, J.-M.; Tard, C.

Phys. Chem. Chem. Phys. 2011, 13 (12), 5353–5358

15. Concerted heavy-atom bond cleavage and proton and electron transfers illustrated by proton-assisted reductive cleavage of an O–O bond

Costentin, C.; Hajj, V.; Robert, M.; Savéant, J.-M.; Tard, C.

Proc. Natl. Acad. Sci. U. S. A. 2011, 108 (21), 8559-8564

14. Inserting a hydrogen-bond relay between proton exchanging sites in proton-coupled electron transfers

Costentin, C.; Robert, M.; Savéant, J.-M.; Tard, C.

Angew. Chem. Int. Ed. 2010, 49 (22), 3803-3806

13. Effect of base pairing on the electrochemical oxidation of guanine

Costentin, C.; Hajj, V.; Robert, M.; Savéant, J.-M.; Tard, C.

J. Am. Chem. Soc. 2010, 132 (29), 10142-10147

12. Coherent nonlinear emission from a single KTP nanoparticle with broadband femtosecond pulses

Wnuk, P.; Xuan, L. L.; Slablab, A.; Tard, C.; Perruchas, S.; Gacoin, T.; Roch, J.-F.; Chauvat, D.; Radzewicz, C.

Opt. Express 2009, 17 (6), 4652-4658

11. Structural and functional analogues of the active sites of the [Fe]-, [NiFe]-, and [FeFe]-hydrogenases

Tard, C.; Pickett, C. J.

Chem. Rev. 2009, 109 (6), 2245-2274

10. Photostable second-harmonic generation from a single KTiOPO4 nanocrystal for nonlinear microscopy

Xuan, L. L.; Zhou, C. Y.; Slablab, A.; Chauvat, D.; Tard, C.; Perruchas, S.; Gacoin, T.; Villeval, P.; Roch, J.-F.

Small 2008, 4 (9), 1332-1336

9. Controlling carbon monoxide binding at di-iron units related to the iron-only hydrogenase sub-site

Xu, F. F.; Tard, C.; Wang, X. F.; Ibrahim, S. K.; Hughes, D. L.; Zhong, W.; Zeng, X. R.; Luo, Q. Y.; Liu, X.; Pickett, C. J.

Chem. Commun. 2008,  (5), 606-608

8. Thermochromic luminescence of sol-gel films based on copper iodide clusters

Tard, C.; Perruchas, S.; Maron, S.; Le Goff, X. F.; Guillen, F.; Garcia, A.; Vigneron, J.; Etcheberry, A.; Gacoin, T.; Boilot, J.-P.

Chem. Mater. 2008, 20 (22), 7010-7016

7. Electropolymeric materials incorporating subsite structures related to iron-only hydrogenase: active ester functionalised poly(pyrroles) for covalent binding of {2Fe3S}-carbonyl/cyanide assemblies

Ibrahim, S. K.; Liu, X.; Tard, C.; Pickett, C. J.

Chem. Commun. 2007,  (15), 1535-1537

6. Modeling [Fe-Fe] hydrogenase: evidence for bridging carbonyl and distal iron coordination vacancy in an electrocatalytically competent proton reduction by an iron thiolate assembly that operates through Fe(0)-Fe(II) levels

Cheah, M. H.; Tard, C.; Borg, S. J.; Liu, X.; Ibrahim, S. K.; Pickett, C. J.; Best, S. P.

J. Am. Chem. Soc. 2007, 129 (36), 11085-11092

5. Balanced homodyne detection of second-harmonic generation from isolated subwavelength emitters

Xuan, L. L.; Brasselet, S.; Treussart, F.; Roch, J.-F.; Marquier, F.; Chauvat, D.; Perruchas, S.; Tard, C.; Gacoin, T.

Appl. Phys. Lett. 2006, 89 (12), 121118-3

4. On the electronic structure of the hydrogenase H-cluster

Schwab, D. E.; Tard, C.; Brecht, E.; Peters, J. W.; Pickett, C. J.; Szilagyi, R. K.

Chem. Commun. 2006,  (35), 3696-3698

3. Iron-only hydrogenase: Synthetic, structural and reactivity studies of model compounds

Liu, X.; Ibrahim, S. K.; Tard, C.; Pickett, C. J.

Coord. Chem. Rev. 2005, 249 (15-16), 1641-1652

2. A novel {FeI-FeII-FeII-FeI} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution

Tard, C.; Liu, X.; Hughes, D. L.; Pickett, C. J.

Chem. Commun. 2005,  (1), 133-135

1. Synthesis of the H-cluster framework of iron-only hydrogenase

Tard, C.; Liu, X.; Ibrahim, S. K.; Bruschi, M.; De Gioia, L.; Davies, S. C.; Yang, X.; Wang, L.-S.; Sawers, G.; Pickett, C. J.

Nature 2005, 433 (7026), 610-613